1559 Proline-rich Proteins as Major Part of the Human Saliva Proteome
A. WALZ1, A. WATTENBERG2, G. SCHMALZ3, M. BLUEGGEL2, and S. RUHL3, 1University of Regensburg, Dental School, Germany, 2Protagen AG, Dortmund, Germany, 3University of Regensburg, Germany

Proline-rich proteins (PRPs) are the major group of proteins in human saliva. Although proteome analysis has been performed on human saliva, no positive identification of proline-rich proteins by a combination of 2D-gelelectrophoresis (2-DE) and mass spectrometry (MS) is available. Objective: The aim of this study was to enlarge the two-dimensional protein map of whole human saliva by including the display of proline-rich proteins in 2D gels and their subsequent identification by mass spectrometry. Methods: Both whole saliva proteins and purified PRP-1 were subjected to isoelectric focusing followed by SDS-PAGE over a pH range between 3-10. Spots were picked, digested, and analyzed by MALDI (matrix assisted laser desorption/ionization)-MS. The data generated were analyzed using protein data base search. Results: New components identified by 2-DE and MS in saliva were actin, cyclophilin B, phosphoglycerate kinase, prolyl-4-hydroxylase, thioredoxin and transferrin. After deviating from the usual database search parameters with regard to trypsin specificity, the identity of PRP-1 could be confirmed by MALDI TOF (time of flight) and MALDI-TOF/TOF. Based on this, an identification of PRPs in saliva was achieved. Interestingly, the proline-rich proteins could only be displayed in 2D-gels when saliva was filtrated with a membrane filter of 0,2 µm pore size. Among the 130 spots identified, 30 spots were acidic proline-rich phosphoproteins, one was proline-rich protein BstNI, subfamiliy 1, and one was proline-rich protein BstNI, subfamily 3. Concerning the acidic proline-rich phosphoproteins an additional peptide peak with a mass of 2136 kDa was detected that was not present in purified PRP-1. The amino acid sequence of this peptide as revealed by peptide-fragmentation-fingerprint (PFF) identified PRP Db (gene PRH1) in saliva. Conclusion: Proline-rich proteins can be displayed by 2D-PAGE and represent, besides salivary amylase, the major part of human salivary proteome.

Supported by grant SFB 585/B5 from the DFG

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